عنوان مقاله [English]
Investigating the leaching amount of trace elements from environmental pollutants such as tailings is very crucial for determining the risk of these materials and sustaining environmental quality. This research was carried out to determine the concentration, risk level and leaching behavior of lead from Zn-Pb mine tailing of Zanjan. For this purpose, two composite samples (0-20 cm) were taken from both types of tailings from the Zn-Pb mine and the pH, time, particle size and liquid to solid ratio was determined using a batch leaching test. Determination of elemental composition and mineralogical characterization of mine tailings were performed using x-ray fluorescence (XRF) and x-ray diffraction (XRD) analytical techniques respectively. The morphology of tailing particles was determined by scanning electron microscope (SEM). For evaluation of tailings risk level, leaching protocols such as Field Leaching Test (FLT), Synthetic Precipitation Leaching Procedure (SPLP), Toxicity Characteristic Leaching Procedure (TCLP) and Leaching Extraction Procedure (LEP) were used. Also, for identification of lead distribution among different fractions of tailings, the sequential extraction method was applied. The concentration of lead in all extracts was measured by ICP-OES. The results showed that the time, particle size, pH and the liquid to solid ratio are more effective on the concentration of lead leaching from tailings and the maximum concentration of lead discharged from the tailings occurred in a different range of particle size. The maximum amounts of lead in the studied tailings were respectively observed in residual, carbonaceous, exchangeable, organic, iron and manganese oxides and solution parts. The results of the leaching protocols also made it clear that both types of waste have great environmental effects and are considered to be hazardous waste residues. Therefore, special measures should be taken to safely store these substances in the environment and prevent lead leaching.
Al-Abed, S. R., Hageman, P. L., Jegadeesan, G., Madhavan, N., & Allen, D. (2006). Comparative evaluation of short-term leach tests for heavy metal release from mineral processing waste. Science of the total Environment, 364(1-3), 14-23
Al-Jabri, K., Taha, R., Al-Hashmi, A., and Al-Harthy, A. (2006). Effect of copper slag and cement by-pass dust addition on mechanical properties of concrete. Construction and building materials, 20(5), 322-331
Brend, L. G. 2007. Mine Wastes, Characterization, Treatment and Environmental Impacts. Springer Pup.
Boyer, R. (1990). The regulation school: a critical introduction: Columbia University Press
Cappuyns, V., Swennen, R., and Deckers, J. (2003). Patterns of metal release in aged and recent dredged sediments during pHstat leaching. Communications in agricultural and applied biological sciences. 68(3), 71-74.
Cao, X., & Dermatas, D. (2008). Evaluating the applicability of regulatory leaching tests for assessing lead leachability in contaminated shooting range soils. Environmental monitoring and assessment, 139(1-3), 1-13
Chand, P., Kumar, A., Gaur, A., and Mahna, S. (2009). Elemental analysis of ash using X-ray fluorescence technique. Asian journal of chemistry
Chandler, A. J., Eighmy, T. T., Hjelmar, O., Kosson, D., Sawell, S., Vehlow, J., Hartlén.,J. (1997). Municipal solid waste incinerator residues (Vol. 67): Elsevier
Colombani, N., Mastrocicco, M., Di Giuseppe, D., Faccini, B., and Coltorti, M. (2015). Batch and column experiments on nutrient leaching in soils amended with Italian natural zeolitites. Catena, 127, 64-71
Çoruh, S., Elevli, S., Ergun, O. N., and Demir, G. (2013). Assessment of leaching characteristics of heavy metals from industrial leach waste. International Journal of Mineral Processing, 123, 165-171
Cote, P., and Constable, T. (1982). Evaluation of experimental conditions in batch leaching procedures. Resources and conservation, 9, 59-73
El-Kamash, A., Zaki, A., and El Geleel, M. A. (2005). Modeling batch kinetics and thermodynamics of zinc and cadmium ions removal from waste solutions using synthetic zeolite A. Journal of hazardous materials, 127(1-3), 211-220.
Enkhzaya, S., Ohe, K., Shiomori, K., Oyuntsetseg, B., Bayanjargal, O., & Watanabe, M. (2016). Assessment of heavy metals in mining tailing around Boroo and Zuunkharaa gold mining areas of Mongolia. Journal of Environmental Science and Technology, 9(5), 379-389
Falagán, C., Grail, B. M., and Johnson, D. B. (2017). New approaches for extracting and recovering metals from mine tailings. Minerals Engineering, 106, 71-78
Fernández-Olmo, I., Lasa, C., Lavín, M. A., and Irabien, A. (2009). Modeling of amphoteric heavy metals solubility in stabilized/solidified steel foundry dust. Environmental Engineering Science, 26(2), 251-262
Grathwohl, P., and Susset, B. (2009). Comparison of percolation to batch and sequential leaching tests: theory and data. Waste Management, 29(10), 2681-2688.
Grathwohl, P., and van der Sloot, H. (2007). Groundwater Risk Assessment at Contaminated Sites (GRACOS): Test Methods and Modelling Approaches. In Groundwater Science and Policy (pp. 291-315).
Guyonnet, D. (2010). Comparison of percolation to batch and sequential leaching tests: Theory and data. Waste Management, 30(8-9), 1746-1747
Hageman, P. L. (2007). US Geological Survey field leach test for assessing water reactivity and leaching potential of mine wastes, soils, and other geologic and environmental materials
Hageman, P. L., and Briggs, P. H. (2000). A simple field leach test for rapid screening and qualitative characterization of mine waste dump material on abandoned mine lands: US Department of the Interior, US Geological Survey
Houben, D., Evrard, L., and Sonnet, P. (2013). Mobility, bioavailability and pH-dependent leaching of cadmium, zinc and lead in a contaminated soil amended with biochar. Chemosphere, 92(11), 1450-1457
Hudson-Edwards, K. A., and Dold, B. (2015). Mine waste characterization, management and remediation. In: Multidisciplinary Digital Publishing Institute
Hudson, C. (2001). The role of international environmental law in the protection of the Danube river basin: the Baia Mare cyanide spill. Colo. J. Int'l Envtl. L. & Pol'y, 12, 367
Iwegbue, C. M. (2013). Chemical fractionation and mobility of heavy metals in soils in the vicinity of asphalt plants in Delta State, Nigeria. Environmental Forensics, 14(3), 248-259
Islam, M. S., Ahmed, M. K., Raknuzzaman, M., Habibullah-Al-Mamun, M., and Masunaga, S. (2015). Metal speciation in sediment and their bioaccumulation in fish species of three urban rivers in Bangladesh. Archives of environmental contamination and toxicology, 68(1), 92-106
Jaishankar, M., Tseten, T., Anbalagan, N., Mathew, B. B., & Beeregowda, K. N. (2014). Toxicity, mechanism and health effects of some heavy metals. Interdisciplinary toxicology, 7(2), 60-72
Janusa, M. A., Bourgeois, J. C., Heard, G. E., Kliebert, N. M., and Landry, A. A. (1998). Effects of particle size and contact time on the reliability of toxicity characteristic leaching procedure for solidified/stabilized waste. Microchemical journal, 59(2), 326-332
Jones, J. M., and Hao, J. (1993). Sequential extraction method: a review and evaluation. Environmental geochemistry and health, 15(2-3), 185
Kabala, C., and Singh, B. R. (2001). Fractionation and mobility of copper, lead, and zinc in soil profiles in the vicinity of a copper smelter. Journal of Environmental Quality, 30(2), 485-492
Kabata-Pendias, A. (1995). Agricultural problems related to excessive trace metal contents of soils. In Heavy metals (pp. 3-18): Springer
Kaniki, A. T., & Tumba, K. (2019). Management of mineral processing tailings and metallurgical slags of the Congolese copperbelt: Environmental stakes and perspectives. Journal of Cleaner Production, 210, 1406-1413
Karaca, O., Cameselle, C., & Reddy, K. R. (2016). Characterization of heavy metals in mine tailings and lake sediments: implications on remediation. In Geo-Chicago 2016 (pp. 12-21).
Karbassi, A., and Shankar, R. (2005). Geochemistry of two sediment cores from the west coast of India. International Journal of Environmental Science & Technology, 1(4), 307-316
Karius, V., and Hamer, K. (2001). pH and grain-size variation in leaching tests with bricks made of harbour sediments compared to commercial bricks. Science of the Total Environment, 278(1-3), 73-85
Kirby, C. S., and Rimstidt, J. D. (1994). Interaction of municipal solid waste ash with water. Environmental Science & Technology, 28(3), 443-451
Katana, C., Jane, M., & Harun, M. (2013). Speciation of zinc and copper in open-air automobile mechanic workshop soils in Ngara area-Nairobi Kenya. Resources and Environment, 3(5), 145-154
Kogbara, R. B. (2011). Process envelopes for and biodegradation within stabilised/solidified contaminated soils. University of Cambridge
Lèbre, É., Corder, G. D., & Golev, A. (2017). Sustainable practices in the management of mining waste: A focus on the mineral resource. Minerals Engineering, 107, 34-42
Lei, M., Zhang, Y., Khan, S., Qin, P.-f., and Liao, B.-h. (2010). Pollution, fractionation, and mobility of Pb, Cd, Cu, and Zn in garden and paddy soils from a Pb/Zn mining area. Environmental monitoring and assessment, 168(1-4), 215-222
Li, F., and Chen, M. (2017). Copper recovery from waste printed circuit boards and the correlation of Cu, Pb, Zn by ionic liquid. Environment Protection Engineering, 43(4).
Li, J.-s., Xue, Q., Fang, L., and Poon, C. S. (2017). Characteristics and metal leachability of incinerated sewage sludge ash and air pollution control residues from Hong Kong evaluated by different methods. Waste Management, 64, 161-170
Liang, S.-x., Wang, X., Li, Z., Gao, N., and Sun, H. (2014). Fractionation of heavy metals in contaminated soils surrounding non-ferrous metals smelting area in the North China Plain. Chemical Speciation & Bioavailability, 26(1), 59-64.
Lim, M., Han, G.-C., Ahn, J.-W., You, K.-S. & Kim, H.-S. (2009). Leachability of arsenic and heavy metals from mine tailings of abandoned metal mines. International journal of environmental research and public health, 6, 2865-2879.
Liu, Y., Qi, T., Chu, J., Tong, Q., and Zhang, Y. (2006). Decomposition of ilmenite by concentrated KOH solution under atmospheric pressure. International Journal of Mineral Processing, 81(2), 79-84
Lottermoser, B. G. (2010). Radioactive Wastes of Uranium Ores. In Mine Wastes (pp. 263-312): Springer
Mendez, M. O., and Maier, R. M. (2007). Phytostabilization of mine tailings in arid and semiarid environments—an emerging remediation technology. Environmental health perspectives, 116(3), 278-283
Montanaro, L., Bianchini, N., Rincon, J. M., and Romero, M. (2001). Sintering behaviour of pressed red mud wastes from zinc hydrometallurgy. Ceramics international, 27(1), 29-37.
Moors, E. H., and Dijkema, G. P. (2006). Embedded industrial production systems: lessons from waste management in zinc production. Technological Forecasting and Social Change, 73(3), 250-265
Nemati, K., Bakar, N. K. A., Abas, M. R., and Sobhanzadeh, E. (2011). Speciation of heavy metals by modified BCR sequential extraction procedure in different depths of sediments from Sungai Buloh, Selangor, Malaysia. Journal of hazardous materials, 192(1), 402-410
Olajire, A., Ayodele, E., Oyedirdan, G., and Oluyemi, E. (2003). Levels and speciation of heavy metals in soils of industrial southern Nigeria. Environmental monitoring and assessment, 85(2), 135-155
Olobatoke, R., and Mathuthu, M. (2016). Heavy metal concentration in soil in the tailing dam vicinity of an old gold mine in Johannesburg, South Africa. Canadian journal of soil science, 96(3), 299-304
Panchal, S., Deb, D., and Sreenivas, T. (2018). Mill tailings based composites as paste backfill in mines of U-bearing dolomitic limestone ore. Journal of Rock Mechanics and Geotechnical Engineering, 10(2), 310-322
Peng, C., Tang, L., Tan, X., Li, Y., Wang, X., Ai, X., and Qiu, J. (2017). Heavy metal fractionation after application of fermented sludge to soil and its effect on sedum lineare. Fresenius Environmental Bulletin, 26(1 A), 810-822
Peralta, G. L. (1997). Characterization, leachability and acid mine drainage potential of geothermal solid residues. National Library of Canada Bibliothèque nationale du Canada
Raskin, I., and Ensley, B. D. (2000). Phytoremediation of toxic metals: John Wiley and Sons.
Restituta Paul M., P. M. S., B and William John Senkondo, M. . (2018). Leaching Behaviour and Speciation of Pb, Zn and Cu in Stabilized Gold Mine Tailings. International Journal of Environmental Monitoring and Protection, 5, 11-17.
Rubinos, D. A., & Barral, M. T. (2013). Fractionation and mobility of metals in bauxite red mud. Environmental Science and Pollution Research, 20(11), 7787-7802
Roussel, C., Bril, H., and Fernandez, A. (2000). Arsenic speciation: involvement in evaluation of environmental impact caused by mine wastes. Journal of Environmental Quality, 29(1), 182-188
Saleem, M., Iqbal, J., Akhter, G., and Shah, M. H. (2018). Fractionation, bioavailability, contamination and environmental risk of heavy metals in the sediments from a freshwater reservoir, Pakistan. Journal of Geochemical Exploration, 184, 199-208
Sauve, S. (2003). The role of chemical speciation in bioavailability. Bioavailability, toxicity and risk relationships in ecosystems, 59-82
Schreck, E., Bonnard, R., Laplanche, C., Leveque, T., Foucault, Y., and Dumat, C. (2012). DECA: a new model for assessing the foliar uptake of atmospheric lead by vegetation, using Lactuca sativa as an example. Journal of environmental management, 112, 233-239
Schultz, M. K., Burnett, W. C., and Inn, K. G. (1998). Evaluation of a sequential extraction method for determining actinide fractionation in soils and sediments. Journal of environmental radioactivity, 40(2), 155-174
Sims, K. W., Gill, J. B., Dosseto, A., Hoffmann, D. L., Lundstrom, C. C., Williams, R. W., and Prytulak, J. (2008). An inter‐laboratory assessment of the thorium isotopic composition of synthetic and rock reference materials. Geostandards and Geoanalytical Research, 32(1), 65-91
Slack, R., and Voulvoulis, N. (2006). Mine Wastes: Characterization, Treatment and Environmental ImpactsBernd G. Lottermoser, Springer-Verlag, Berlin, Heidelberg, New York, 2003, ISBN: 3-540-00526-9 (277 pp., Hardback). In: Elsevier
Sposito GLJL, A. C. C. (1982). Trace Metal Chemistry in Arid-zone Field Soils Amended with Sewage Sludge: I.Fractionation of Ni, Cu, Zn, Cd, and Pb in Solid Phases. Soil Science Society of America Journal., 46, 260-274
Sundaray, S. K., Nayak, B. B., Lin, S., and Bhatta, D. (2011). Geochemical speciation and risk assessment of heavy metals in the river estuarine sediments—a case study: Mahanadi basin, India. Journal of hazardous materials, 186(2-3), 1837-1846
Tessier, A., Campbell, P. G., and Bisson, M. (1979). Sequential extraction procedure for the speciation of particulate trace metals. Analytical chemistry, 51(7) , 844-851.
Tiwari, M. K., Bajpai, S., Dewangan, U. K., and Tamrakar, R. K. (2015). Suitability of leaching test methods for fly ash and slag: A review. Journal of Radiation Research and Applied Sciences, 8, 523-537.
USEPA. (2004). Characteristics Introduction and Regulatory Definitions, TestMethods for Evaluating Solid Waste, Physical/Chemical Methods (SW 846). US Environmental Protection Agency
USEPA. (1992). Method 1311, Toxicity Characteristic Leaching Procedure (TCLP). Publication SW)846: Test Methods for Evaluating Solid Waste, Physical/Chemical Methods. www. epa.gov/epaoswer/hazwaste/test/pdfs/1311.pdf.
USEPA, (1994). Synthetic precipitation leaching procedure (SPLP). EPA Method 1312, Washington, USA.
USEPA, (1989). Stabilization/Solidification of CERCLA and RCRA Wastes, EPA/625/6-89/022.
Van der Sloot, H., Kosson, D., and Hjelmar, O. (2001). Characteristics, treatment and utilization of residues from municipal waste incineration. Waste Management, 21(8), 753-765
Van Herck, P., Van der Bruggen, B., Vogels, G., and Vandecasteele, C. (2000). Application of computer modelling to predict the leaching behaviour of heavy metals from MSWI fly ash and comparison with a sequential extraction method. Waste Management, 20(2-3), 203-210
Verplanck, P. L. 2008. Understanding contaminants associated with mineral deposits. Geological Survey (US).
Vodyanitskii, Y. N. (2016). Standards for the contents of heavy metals in soils of some states. annals of agrarian science, 14(3), 257-263.
World Health Organization. (2004). Guidelines for drinking-water quality (Vol. 1).
Yang, H., Liu, J., and Yang, J. (2011). Leaching copper from shredded particles of waste printed circuit boards. Journal of hazardous materials, 187(1-3), 393-400
Yang, S., Cao, J., Hu, W., Zhang, X., and Duan, C. (2013). An evaluation of the effectiveness of novel industrial by-products and organic wastes on heavy metal immobilization in Pb–Zn mine tailings. Environmental Science: Processes & Impacts, 15(11), 2059-2067
Ye, C., He, F., Shu, H., Qi, H., Zhang, Q., Song, P., and Xie, J. (2015). Preparation and properties of sintered glass–ceramics containing Au–Cu tailing waste. Materials & Design, 86, 782-787
Younger, P. L., and Wolkersdorfer, C. (2004). Mining impacts on the fresh water environment: technical and managerial guidelines for catchment scale management. Mine water and the environment, 23, s2-s80
Zandi, M., and Russell, N. V. (2007). Design of a leaching test framework for coal fly ash accounting for environmental conditions. Environmental monitoring and assessment, 131(1-3), 509-526.
Zhang, Y., Jiang, J., and Maozhe, C. (2008). MINTEQ modeling for evaluating the leaching behavior of heavy metals in MSWI fly ash. Journal of Environmental Sciences, 20(11), 1398-1402
Zinck, J., Wilson, L., Chen, T., Griffith, W., Mikhail, S., and Turcotte, A. (1997). Characterization and stability of acid mine drainage treatment sludges. Mining and Mineral Sciences Laboratories Report, 96-079.