نوع مقاله : مقاله پژوهشی
نویسندگان
1 دانشیار گروه علوم خاک، دانشکده کشاورزی، دانشگاه ملایر، ملایر، ایران
2 گروه علوم خاک، دانشکده کشاورزی، دانشگاه ملایر، ملایر، ایران
3 گروه مهندسی عمران، دانشکده عمران و معماری، دانشگاه ملایر، ملایر، ایران
چکیده
کلیدواژهها
موضوعات
عنوان مقاله [English]
نویسندگان [English]
Water pollution caused by the discharge of industrial wastewater containing reactive dyes, especially from the textile industry, has become one of the major environmental challenges. Azo dyes such as Remazol Black B (RB-B) and Lovafix Blue (LBB) are common pollutants in these wastewaters due to their high stability and widespread use. In this study, the efficiency of nickel oxide (NiO) nanoparticles in the removal of these two dyes by adsorption was investigated. Experiments aimed at determining the optimal conditions were conducted across various ranges of pH (3 to 8), adsorbent dosage (1 to 5 g/L), temperature (20 to 40 °C), and contact time (10 to 180 minutes). The structure and surface properties of the adsorbent were characterized using SEM, EDX, XRD, BET, and FTIR analyses. The results showed that NiO nanoparticles with an average size of approximately 45.67 nm and a specific surface area of 127.18 m²/g exhibited high adsorption capacity. The optimum conditions for the adsorption of RB-B were achieved at pH 7, and for LBB at pH 8. The maximum adsorption capacities for RB-B and LBB were 17.49 mg/g and 13.83 mg/g, respectively. The pseudo-second-order kinetic model (R² = 0.999) and Temkin isotherm model (R² = 0.942) provided the best fit to the data. Furthermore, thermodynamic data confirmed that the process was endothermic and spontaneous. Overall, the results of this study indicate that NiO nanoparticles, due to their effective and cost-efficient performance in dye removal, can be utilized for semi-industrial and industrial wastewater treatment in textile industries.
کلیدواژهها [English]
The discharge of colored wastewater from various industries, especially aromatic dye compounds with complex structures and high water solubility, creates serious environmental problems as they are toxic, carcinogenic, and non-biodegradable. Azo dyes, including Remazol Black B (RB-B) and Levafix Blue (LBB), are considered common pollutants in effluents due to their stability and widespread use in the textile industry. Adsorption, due to its efficiency, economic viability, and environmental compatibility, has attracted attention as an effective method for removing these pollutants. Nickel oxide (NiO) nanoparticles, owing to their unique magnetic, electronic, and optical properties, are suitable adsorbents for treating colored wastewater. However, specific and comprehensive studies on the removal of Remazol Black B and Levafix Blue dyes using nickel oxide nanoparticles have been less frequently reported in domestic scientific sources. The aim of this research was to investigate the efficiency of nickel oxide nanoparticles for the removal of these two dyes from aqueous solutions by examining the effect of parameters including adsorbent dosage, pH, temperature, and contact time.
In this study, Remazol Black B and Levafix Blue dyes (Sangchun Company, South Korea) and nickel oxide nanoparticles were used as adsorbents. The pH of the solutions was adjusted with HCl and NaOH, and dye concentrations were measured using an Analytik Jena 205 UV-Vis spectrophotometer. Adsorption experiments were conducted using the One-Factor-At-a-Time (OFAT) method to investigate the effect of various parameters including adsorbent dosage (1-5 g/L), pH (3-8), temperature (20-40 °C), and contact time (60-180 minutes). The structural characteristics of NiO were determined by FTIR, SEM, XRD, and EDX analyses. Adsorption capacity and removal efficiency were calculated. Adsorption kinetics and isotherms (Langmuir, Freundlich, Temkin) were also investigated.
NiO Nanoadsorbent Characterization: SEM images showed that NiO nanoparticles have a dense morphology with sizes around 45.67 nm, creating a porous and active surface for adsorption. EDX analysis confirmed the presence of nickel and oxygen elements, indicating the high purity of the nanoadsorbent. FTIR spectroscopy identified O-H and C-O functional groups and Ni-O bonds. XRD analysis determined the average crystallite size to be 94.4 nm. The specific surface area of the adsorbent, as determined by BET, was reported as 127.18 m²/g.
Effect of Adsorbent Dosage: Increasing the adsorbent dosage from 1 to 5 g/L increased the removal efficiency for Levafix Blue dye by up to 47.17% and for Remazol Black B dye from 65.72% to 93.85%. An optimal adsorbent dosage of 5 g/L was selected for both dyes.
Effect of pH: Maximum removal efficiency for Remazol Black B dye was observed at pH 7 (approximately 96%) and for Levafix Blue dye at pH 8 (approximately 94.1%). These results indicate that alkaline conditions are more favorable for the removal of these dyes.
Effect of Temperature and Thermodynamics: Increasing the temperature from 20 to 35 °C increased the adsorption efficiency for both dyes. A temperature of 35 °C was identified as the optimal temperature, at which the removal efficiency for Remazol Black B was 96.75% and for Levafix Blue was 98.22%. Thermodynamic results showed that the adsorption process for both dyes was spontaneous (ΔG<0) and endothermic (ΔH>0), and accompanied by an increase in disorder (ΔS>0).
Effect of Contact Time: The time to reach adsorption equilibrium for both dyes was determined to be approximately 180 minutes. At this time, the adsorption efficiency for Remazol Black B increased to approximately 99% and for Levafix Blue to approximately 91%.
Adsorption Isotherms and Kinetics: Levafix Blue dye followed the Temkin adsorption isotherm model, while Remazol Black B did not show a sufficient fit with the models investigated. Kinetic results showed that the adsorption of both dyes followed the pseudo-second-order model. The maximum adsorption capacity obtained was 13.83 mg/g for Levafix Blue and 17.49 mg/g for Remazol Black B. The removal efficiency for Levafix Blue was reported as 94.6% and for Remazol Black B as 97.25%.
Nickel oxide nanoadsorbent was introduced as an effective adsorbent for the removal of Remazol Black B and Levafix Blue dyes from contaminated wastewater. The optimal conditions for Remazol Black B removal included pH 7, adsorbent dosage of 5 g/L, temperature of 35 °C, and contact time of 180 minutes, with a maximum efficiency of 87.45% and an adsorption capacity of 17.49 mg/g. For Levafix Blue, the optimal conditions were determined to be pH 8, adsorbent dosage of 5 g/L, temperature of 35 °C, and contact time of 180 minutes, with a maximum efficiency of 69.16% and an adsorption capacity of 13.83 mg/g. The adsorption process for both dyes was spontaneous and endothermic, and followed pseudo-second-order kinetics. This research paves the way for the development of effective and cost-efficient methods for treating textile industry dye wastewater.
Conceptualization and idea development: First author; Experimental work and data collection: Second author; Final editing and data review: Third author; Data analysis: Fourth author. All authors have read and approved the final version of the manuscript.
The data are available upon request from the corresponding author via email (Smahdaviha@yahoo.com).
This research was conducted in the Soil Chemistry Research Laboratory, Department of Soil Science and Engineering, Faculty of Agriculture, Malayer University.
The authors avoided data fabrication, falsification, plagiarism, and misconduct.
The author declares no conflict of interest.
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