Investigation of Water Hardness Reduction (Ca+Mg) using Strong Cationic Resins

Document Type : Research Paper

Authors

1 MSc student of Irrigation and Drainage, Faculty of Agricultural Engineering, Water Engineering Department, Sari Agricultural Sciences and Natural Resources University, Sari, Iran.

2 Assistant Professor, Water Engineering Department, Faculty of Agricultural Engineering, Sari Agricultural Sciences and Natural Resources University, Sari, Iran.

3 Instructor, Water Engineering Department, Faculty of Agricultural Engineering, Sari Agricultural Sciences and Natural Resources University, Sari, Iran.

Abstract

Due to the high cost of water treatment by chemicals, low cost methods of refinement are very important. In this study, four types of strong cationic resins including Purolite C100, Purolite C100E, Trilite SCR-B and Dowex Marathon C as softening with different levels of 3, 5, 8 and 10 liters used to reduce Ca and Mg ions in Water Supply Station of the Coal Village House in Juybar city, Mazandaran province. In this study, Factorial experiments carried out in a completely randomized design to investigate the effect of different types and amounts of resins on Ca and Mg reduction in water. The results showed that the three liters of Dowex Marathon C resin have the highest removal efficiency of 16.1 and 21.5%, respectively, for magnesium and calcium. In addition, the five liters of Trilitle SCR-B resin have the removal efficiency of 37.4% and 42.5% for Mg and Ca, respectively. The eight liters of Trilitle SCR-B resin have the removal efficiency of 51.6% for magnesium and 60.3% for calcium. The highest removal efficiency of Mg (66%) and Ca (77.6%) obtained by using 10 liters Purolitle C100e and Trilitle SCR-B resins, respectively. Finally, it can be said that the Trilite SCR-B resin with the lowest calcium and magnesium hardness in the water (36 and 16 mg/l respectively) and the most effectiveness on hardness reduction is suggested to be used in the water treatment system of Juybar city.

Keywords

Main Subjects


Aghakhani, A., Mousavi, S. F., Mostafazadeh-Fard, B., Rostamian, R., & Seraji, M. 2011. Application of some combined adsorbents to remove salinity parameters from drainage water. Desalination, 275(1-3): 217-223.‏
Asemanrafat, M., Tabatabaei, S. J., & Noshadi, M. 2013. Absorption of heavy elements of lead, nickel and cadmium with cationic resin amberlite IR120. Iranian Water Researches Journal, 13(7): 197-204.
Bolto, B., Dixon, D., & Eldridge, R. 2004. Ion exchange for the removal of natural organic matter. Reactive and Functional Polymers, 60: 171-182.‏
Comstock, S. E., & Boyer, T. H. 2014. Combined magnetic ion exchange and cation exchange for removal of DOC and hardness. Chemical Engineering Journal, 241: 366-375.‏
Emerson, A. G. D. 2003. Quantitative Forecasting of Problems in Industrial Water Systems. World Scientific Publishing Company.‏
Farzaneh, F., Shivapour, Z., Khosravi, T. N., & Sayyad, M. J. 2001. Study on sorption of some toxic and heavy ions in dilute solutions by Clinoptilolite.‏ Journal of Sciences, 12(3): 223-231.
Gholami, M., M. Do. Kishkoli, & M. Shaheed Beyhestani. 2010. Effective factors on the efficiency of under-pressurized sand filters in rural drinking water treatment plants in Ahvaz. 4th Environmental Engineering Conference, Tehran, University of Tehran, Environmental Faculty, 9 p. (In Farsi)
Golshahi, A. 2012. The role of ion exchangers in reducing water hardness. Master's thesis, Semnan University. (In Farsi)
Júnior, O. K., Gurgel, L. V. A., & Gil, L. F. 2010. Removal of Ca (II) and Mg (II) from aqueous single metal solutions by mercerized cellulose and mercerized sugarcane bagasse grafted with EDTA dianhydride (EDTAD). Carbohydrate Polymers, 79(1): 184-191.‏
Malchuthan, M., Blush, Fatehizadeh, A. S., & Ihram, M. 2010. Evaluation of Nano-Filter Efficiency in Removal of Calcium and Magnesium Elements from Artificial Water Samples in Different Operating Conditions. Journal of Yazd School of Public Health, 9(4): 10-19. (In Farsi)
Mirzaei, M. J. 2014. The effect of ion-exchange resin, almond shell, bentonite and hydroxyapatite on irrigation water salinization in nano and micro scale. Master's thesis, Shahr-e-kord University. (In Farsi)
Picari, M., & Carbasian, W. 2015. Water experiments. Arkan Danesh Publication, 178 p. (In Farsi)
Pilgrimage, M. C. & Kindof, M. 2016. Removal of heavy metal iodine from industrial water by cationic ion exchange resins as a sorbent. Third International Conference on Recent Advances in Chemistry and Chemical Engineering, Tehran, International Federation of Inventors of the World (IFIA), 13 p. (In Farsi)
Ping, Q., Cohen, B., Dosoretz, C., & He, Z. 2013. Long-term investigation of fouling of cation and anion exchange membranes in microbial desalination cells. Desalination, 325: 48-55.‏
Rengaraj, S., Yeon, K. H., & Moon, S. H. 2001. Removal of chromium from water and wastewater by ion exchange resins. Journal of hazardous materials, 87(1-3): 273-287.‏
Sadeghi, Sh. 2018. Use of ion exchange resins to reduce Booshehr province's hardness and drinking water's TDS to prevent corrosion and deposition. Master's Thesis, Persian Gulf University. (In Farsi)
Shams, M., Mohamadi, A., & Sajadi, S. A. 2012. Evaluation of corrosion and scaling potential of water in rural water supply distribution networks of Tabas, Iran. World Appl Sci J, 17(11): 1484-89.‏
Yu, Z., Qi, T., Qu, J., Wang, L., & Chu, J. 2009. Removal of Ca (II) and Mg (II) from potassium chromate solution on Amberlite IRC 748 synthetic resin by ion exchange. Journal of hazardous materials, 167(1-3): 406-412.‏
Zak, G. M., Mancini, N. D., & Mitsos, A. 2013. Integration of thermal desalination methods with membrane-based oxy-combustion power cycles. Desalination, 311: 137-149.‏
Zashedis crying, A. S., & Mastouri, R. 2016. Investigation of Water Treatment Process in Water Treatment Plant (Case Study of Gorgan Reservoir). The Second International Conference on Sustainable Development, Strategies and Challenges Focusing on Agriculture, Natural Resources, Environment and Tourism, Tabriz, Permanent Secretariat of the International Conference on Sustainable Development, Solutions and Challenges, p. (In Farsi)
Chalcash Amiri, M. 2016. Separation of gross particles from millimeters (suspended matter) to angstrom (soluble quad). First Edition, Arkan Danesh press, Esfahan. (In Farsi)